Making More-Complex Molecules Using Superthermal Atom/Molecule Collisions
- Created: Monday, 01 September 2008
Atoms adsorbed on cold surfaces react with energetic impinging atoms.
A method of making more-complex molecules from simpler ones has emerged as a by-product of an experimental study in outer-space atom/ surface collision physics. The subject of the study was the formation of CO2 molecules as a result of impingement of O atoms at controlled kinetic energies upon cold surfaces onto which CO molecules had been adsorbed. In this study, the O/CO system served as a laboratory model, not only for the formation of CO2 but also for the formation of other compounds through impingement of rapidly moving atoms upon molecules adsorbed on such cold interstellar surfaces as those of dust grains or comets. By contributing to the formation of increasingly complex molecules, including organic ones, this study and related other studies may eventually contribute to understanding of the origins of life.
Generalizing the method used in this study, it may be possible, for example, to make simple and more-complex amines, even amino acids by reacting ice mixtures of CH4 and NH3 with superthermal O and H beams. In general, by choice of atomic projectiles, kinetic energies, atomic quantum states, surfaces, and exposure times, it may be possible to create new molecular species and stabilize them on the solid surfaces on which they were created.
This work was done by Brian Shortt, Ara Chutjian, and Otto Orient of Caltech for NASA’s Jet Propulsion Laboratory.
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