Batteries could get an upgrade from an Oak Ridge National Laboratory discovery that increases power, energy density, and safety while reducing charge time. The results could also have significance for applications in stationary energy storage systems for solar and wind power, and for smart grids.
A team led by Hansan Liu, Gilbert Brown, and Parans Paranthaman of the Chemical Sciences Division found that titanium dioxide creates a highly desirable material that increases surface area and features a fast charge-discharge capability for lithium ion batteries.
"We can charge our battery to 50 percent of full capacity in six minutes while the traditional graphite-based lithium ion battery would be just 10 percent charged at the same current," Liu said.
Compared to commercial lithium titanate material, the ORNL compound also boasts a higher capacity - 256 vs. 165 milliampere hour per gram - and a sloping discharge voltage that is good for controlling state of charge. This characteristic combined with the fact oxide materials are extremely safe and long-lasting alternatives to commercial graphite make it well-suited for hybrid electric vehicles and other high-power applications.
The titanium dioxide with a bronze polymorph also has the advantage of being potentially inexpensive, according to Liu.
At the heart of the breakthrough is the novel architecture of titanium dioxide, named mesoporous TiO2-B microspheres, which features channels and pores that allow for unimpeded flow of ions with a capacitor-like mechanism. Consequently, a lithium ion battery that substitutes TiO2-B for the graphite electrode charges and discharges quickly.
"Theoretical studies have uncovered that this pseudocapacitive behavior originates from the unique sites and energetics of lithium absorption and diffusion in TiO2-B structure," the researchers said.
Paranthaman noted that the microsphere shape of the material allows for traditional electrode fabrication and creates compact electrode layers. He also observed, however, that the production process of this material is complex and involves many steps, so more research remains to determine whether it is scalable.