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Sandwich-Like Structures for Efficient Hydrogen Fuel Cells

Making hydrogen fuel cells practical on a large scale requires them to be more efficient and cost effective, and a research team from the University of Central Florida may have found a way around both hurdles.

The majority of hydrogen fuel cells use catalysts made of a rare and expensive metal – platinum. There are few alternatives because most elements can’t endure the fuel cell’s highly acidic solvents present in the reaction that converts hydrogen’s chemical energy into electrical power. Only four elements can resist the corrosive process – platinum, iridium, gold, and palladium. The first two are rare and expensive, which makes them impractical for large-scale use. The other two don’t do well with the chemical reaction.

UCF Professor Sergey Stolbov and postdoctoral research associate Marisol Alcántara Ortigoza focused on making gold and palladium better suited for the reaction. They created a sandwich-like structure that layers cheaper and more abundant elements with gold and palladium and other elements to make it more effective. The outer monoatomic layer (the top of the sandwich) is either palladium or gold. Below it is a layer that works to enhance the energy conversion rate but also acts to protect the catalyst from the acidic environment. These two layers reside on the bottom slice of the sandwich — an inexpensive substrate (tungsten), which also plays a role in the stability of the catalyst.

By creating these structures, more energy is converted, and because the more expensive and rare metals are not used, the cost could be significantly less.

(University of Central Florida)