Burn-Resistant, Strong Metal-Matrix Composites

Ceramic particulate fillers increase burn resistances and specific strengths of metals.

Ceramic particulate fillers increase the specific strengths and burn resistances of metals: This is the conclusion drawn by researchers at Johnson Space Center's White Sands Test Facility. The researchers had theorized that the inclusion of ceramic particles in metal tools and other metal objects used in oxygen-rich atmospheres (e.g., in hyperbaric chambers and spacecraft) could reduce the risk of fire and the consequent injury or death of personnel. In such atmospheres, metal objects act as ignition sources, creating fire hazards. However, not all metals are equally hazardous: some are more burn-resistant than others are. It was the researchers' purpose to identify a burn-resistant, high-specific-strength ceramic-particle/metal-matrix composite that could be used in oxygen-rich atmospheres.

Posted in: Briefs, Materials, Aluminum alloys, Ceramics, Composite materials, Materials properties, Fire

Better VPS Fabrication of Crucibles and Furnace Cartridges

The choice of alloy composition and processing parameters is important.

An experimental investigation has shown that by (1) vacuum plasma spraying (VPS) of suitable refractory metal alloys on graphite mandrels, and then (2) heat-treating the VPS alloy deposits under suitable conditions, it is possible to fabricate improved crucibles and furnace cartridges that could be used at maximum temperatures between 1,400 and 1,600 °C and that could withstand chemical attack by the materials to be heated in the crucibles and cartridges. Taken by itself, the basic concept of fabricating furnace cartridges by VPS of refractory materials onto graphite mandrels is not new; taken by itself, the basic concept of heat treatment of VPS deposits for use as other than furnace cartridges is also not new; however, prior to this investigation, experimental crucibles and furnace cartridges fabricated by VPS had not been heat treated and had been found to be relatively weak and brittle. Accordingly, the investigation was directed toward determining whether certain combinations of (1) refractory alloy compositions, (2) VPS parameters, and (3) heat-treatment parameters could result in VPS-fabricated components with increased ductility.

Posted in: Briefs, TSP, Materials, Fabrication, Alloys, Materials properties, Refractory materials

Antistatic Polycarbonate/Copper Oxide Composite

Surface resistance lies in the desired range.

A composite material consisting of polycarbonate filled with copper oxide has been found to be suitable as an antistatic material. This material was developed to satisfy a requirement for an antistatic material that has a mass density less than that of aluminum and that exhibits an acceptably low level of outgassing in a vacuum.

Posted in: Briefs, TSP, Materials, Composite materials, Copper alloys, Lightweight materials, Materials properties, Polymers

Stable, Thermally Conductive Fillers for Bolted Joints

A commercial structural epoxy [Super Koropon (or equivalent)] has been found to be a suitable filler material for bolted joints that are required to have large thermal conductances. The contact area of such a joint can be less than 1 percent of the apparent joint area, the exact value depending on the roughnesses of the mating surfaces. By occupying the valleys between contact peaks, the filler widens the effective cross section for thermal conduction. In comparison with prior thermal joint-filler materials, the present epoxy offers advantages of stability, ease of application, and —as a byproduct of its stability — lasting protection against corrosion. Moreover, unlike silicone greases that have been used previously, this epoxy does not migrate to contaminate adjacent surfaces. Because this epoxy in its uncured state wets metal joint surfaces and has low viscosity, it readily flows to fill the gaps between the mating surfaces: these characteristics affect the overall thermal conductance of the joint more than does the bulk thermal conductivity of the epoxy, which is not exceptional. The thermal conductances of metal-to-metal joints containing this epoxy were found to range between 5 and 8 times those of unfilled joints.

Posted in: Briefs, TSP, Materials, Heat transfer, Fastening, Adhesives and sealants, Conductivity, Metals, Performance tests

Shields for Enhanced Protection Against High-Speed Debris

A report describes improvements over the conventional Whipple shield (two thin, spaced aluminum walls) for protecting spacecraft against high-speed impacts of orbiting debris. The debris in question arises mainly from breakup of older spacecraft. The improved shields include exterior "bumper" layers composed of hybrid fabrics woven from combinations of ceramic fibers and high-density metallic wires or, alternatively, completely metallic outer layers composed of high-strength steel or copper wires. These shields are designed to be light in weight, yet capable of protecting against orbital debris with mass densities up to about 9 g/cm3, without generating damaging secondary debris particles. As yet another design option, improved shields can include sparsely distributed wires made of shape memory metals that can be thermally activated from compact storage containers to form shields of predetermined shape upon arrival in orbit. The improved shields could also be used to augment shields installed previously.

Posted in: Briefs, TSP, Materials, Particulate matter (PM), Performance upgrades, Impact tests, Protective structures, Spacecraft

Transparent Metal-Salt-Filled Polymeric Radiation Shields

These shields offer advantages over ones made from lead foil or leaded glass.

The Quantitative and Qualitative Parameters in this table are those of three shields that give equivalent protection against ionizing radiation.

"COR-RA" (colorless atomic oxygen resistant — radiation shield) is the name of a transparent polymeric material filled with x-ray-absorbing salts of lead, bismuth, cesium, and thorium. COR-RA is suitable for use in shielding personnel against bremsstrahlung radiation from electron-beam welding and industrial and medical x-ray equipment. In comparison with lead- foil and leaded- glass shields that give equivalent protection against x-rays (see table), COR-RA shields are mechanically more durable.

Posted in: Briefs, TSP, Materials, Personnel, Composite materials, Polymers, Protective equipment, Radiation protection

Meshed-Pumpkin Super-Pressure Balloon Design

Masses of long-life, high-altitude balloons could be decreased substantially.

An improved, lightweight design has been proposed for super-pressure balloons used to carry scientific instruments at high altitudes in the atmosphere of Earth for times as long as 100 days. [A super- pressure balloon is one in which the pressure of the buoyant gas (typically, helium) is kept somewhat above ambient pressure in order to maintain approximately constant density and thereby regulate the altitude.] The proposed design, called "meshed pumpkin," incorporates the basic concept of the pumpkin design, which is so named because of its appearance (see figure). The pumpkin design entails less weight than does a spherical design, and the meshed-pumpkin design would reduce weight further.

Posted in: Briefs, TSP, Materials, Elastomers, Fabrics, Gases, Lightweighting, Unmanned aerial vehicles

Corrosion Inhibitors as Penetrant Dyes for Radiography

These substances now have dual uses.

A Weld Crack Is More Clearly Visible in a neutron radiograph made after treatment with an LVCI.

Liquid/vapor-phase corrosion inhibitors (LVCIs) have been found to be additionally useful as penetrant dyes for neutron radiography (and perhaps also x-radiography). Enhancement of radiographic contrasts by use of LVCIs can reveal cracks, corrosion, and other defects that may be undetectable by ultrasonic inspection, that are hidden from direct optical inspection, and/or that are difficult or impossible to detect in radiographs made without dyes.

Posted in: Briefs, Materials, Coatings, colorants, and finishes, Corrosion, Radiation, X-ray inspections

Explicit Pore Pressure Material Model in Carbon-Cloth Phenolic

The explicit model predicts some quantities that a prior implicit model cannot.

An explicit material model that uses predicted pressure in the pores of a carbon-cloth phenolic (CCP) composite has been developed. This model is intended to be used within a finite-element model to predict phenomena specific to CCP components of solid-fuel-rocket nozzles subjected to high operating temperatures and to mechanical stresses that can be great enough to cause structural failures. Phenomena that can be predicted with the help of this model include failures of specimens in restrained-thermal-growth (RTG) tests, pocketing erosion, and ply lifting.

Heretofore, an implicit formulation has been used to model the pore pressure. The differences between explicit and implicit models can be illustrated with the theoretical solution for stress and strain in an RTG test. The equations for the explicit case are:

Posted in: Briefs, Materials, Finite element analysis, Solid propellants, Composite materials, Materials properties, Nozzles, Rocket engines

Treatment To Destroy Chloro-hydrocarbon Liquids in the Ground

Emulsified iron is injected into the ground and left there.

A relatively simple chemical treatment that involves the use of emulsified iron has been found to be effective in remediating groundwater contaminated with trichloroethylene and other dense chlorohydrocarbon liquids. These liquids are members of the class of dense, non-aqueous phase liquids (DNAPLs), which are commonly recognized to be particularly troublesome as environmental contaminants. The treatment converts these liquids into less-harmful products.

Posted in: Briefs, TSP, Materials, Hydrocarbons, Land pollution, Water pollution, Water treatment, Chemicals, Iron

The U.S. Government does not endorse any commercial product, process, or activity identified on this web site.