Materials & Coatings

Processable Polyimides Containing APB and Reactive End Caps

Properties can be tailored through choice of proportions of dianhydrides and APB. Imide copolymers that contain 1,3-bis (3- aminophenoxy) benzene (APB) and other diamines and dianhydrides and that are terminated with appropriate amounts of reactive end caps have been invented. The reactive end caps investigated thus far include 4-phenylethynyl phthalic anhydride (PEPA), 3-amino- phenoxy-4'- phenylethynyl benzophenone (3-APEB), maleic anhydride (MA), and 5-norbornene-2,3-dicarboxylic anhydride [also known as nadic anhydride (NA)]. The advantage of these copolyimides terminated with reactive groups, relative to other polyimides terminated with reactive groups, is a combination of (1) higher values of desired mechanical-property parameters and (2) greater ease of processing into useful parts.

Posted in: Briefs, TSP, Materials

Read More >>

Liquid Coatings for Reducing Corrosion of Steel in Concrete

Structures could be protected more easily and less expensively. Inorganic coating materials are being developed to slow or stop corrosion of reinforcing steel members inside concrete structures. It is much simpler and easier to use these coating materials than it is to use conventional corrosion-inhibiting systems based on impressed electric currents. Unlike impressed electrical corrosion-inhibiting systems, these coatings do not require continuous consumption of electrical power and maintenance of power-supply equipment. Whereas some conventional systems involve the use of expensive arc-spray equipment to apply the metallic zinc used as the sacrificial anode material, the developmental coatings can be applied by use of ordinary paint sprayers.

Posted in: Briefs, Materials

Read More >>

Less-Toxic Coatings for Inhibiting Corrosion of Aluminum

It is no longer necessary to use highly toxic and carcinogenic chromates. Two recently invented families of conversion- coating processes have been found to be effective in reducing or preventing corrosion of aluminum alloys. These processes offer less-toxic alternatives to prior conversion- coating processes that are highly effective but have fallen out of favor because they generate chromate wastes, which are toxic and carcinogenic. Specimens subjected to these processes were found to perform well in standard salt-fog corrosion tests.

Posted in: Briefs, Materials

Read More >>

Organic/Inorganic Hybrid Polymer/Clay Nanocomposites

The exfoliation and dispersion of clay particles are improved. A novel class of polymer/clay nanocomposites has been invented in an attempt to develop transparent, lightweight, durable materials for a variety of aerospace applications. As their name suggests, polymer/clay nanocomposites comprise organic/ inorganic hybrid polymer matrices containing platelet- shaped clay particles that have sizes of the order of a few nanometers thick and several hundred nanometers long. Partly because of their high aspect ratios and high surface areas, the clay particles, if properly dispersed in the polymer matrix at a loading level of 1 to 5 weight percent, impart unique combinations of physical and chemical properties that make these nanocomposites attractive for making films and coatings for a variety of industrial applications. Relative to the unmodified polymer, the polymer/clay nanocomposites may exhibit improvements in strength, modulus, and toughness; tear, radiation, and fire resistance; and lower thermal expansion and permeability to gases while retaining a high degree of optical transparency.

Posted in: Briefs, Materials

Read More >>

Functionally Graded Nanophase Beryllium/Carbon Composites

The main advantage, relative to Co/WC/diamond composites, is less weight. Beryllium, beryllium alloys, beryllium carbide, and carbon are the ingredients of a class of nanophase Be/Be2C/C composite materials that can be formulated and functionally graded to suit a variety of applications. In a typical case, such a composite consists of a first layer of either pure beryllium or a beryllium alloy, a second layer of B2C, and a third layer of nanophase sintered carbon derived from fullerenes and nanotubes. The three layers are interconnected through interpenetrating spongelike structures.

Posted in: Briefs, TSP, Materials

Read More >>

Thin Thermal-Insulation Blankets for Very High Temperatures

One blanket would have about the thickness of several sheets of paper. Thermal-insulation blankets of a proposed type would be exceptionally thin and would endure temperatures up to 2,100 °C. These blankets were originally intended to protect components of the NASA Solar Probe spacecraft against radiant heating at its planned closest approach to the Sun (a distance of 4 solar radii). These blankets could also be used on Earth to provide thermal protection in special applications (especially in vacuum chambers) for which conventional thermal-insulation blankets would be too thick or would not perform adequately.

Posted in: Briefs, TSP, Materials

Read More >>

Multiaxial Temperature- and Time-Dependent Failure Model

This model should be applicable to a variety of materials. A temperature- and time-dependent mathematical model predicts the conditions for failure of a material subjected to multiaxial stress. The model was initially applied to a filled epoxy below its glass-transition temperature, and is expected to be applicable to other materials, at least below their glass-transition temperatures. The model is justified simply by the fact that it closely approximates the experimentally observed failure behavior of this material: The multiaxiality of the model has been confirmed (see figure) and the model has been shown to be applicable at temperatures from —20 to 115 °F (–29 to 46 °C) and to predict tensile failures of constant-load and constant-load-rate specimens with failure times ranging from minutes to months.

Posted in: Briefs, Materials

Read More >>

White Papers

Electropolishing for Hydraulics and Pneumatics
Sponsored by Able Electropolishing
External Power Supply Efficiency Regulation Introduction
Sponsored by MEGA Electronics
Developing Secure Embedded Software
Sponsored by PRQA
Controlling the EMI Effects of Avionic Equipment
Sponsored by Orbel
Sense Element Pump Ripple Fatigue
Sponsored by Hydra Electric
The Ultimate Shaft-To-Hub Connection
Sponsored by Stoffel Polygon

White Papers Sponsored By:

The U.S. Government does not endorse any commercial product, process, or activity identified on this web site.