Materials

Direct Electrolytic Deposition of Mats of MnxOy Nanowires

These mats of nanowires can be used as electrodes for batteries and capacitors. Mats of free-standing manganese oxide (MnxOy ) nanowires have been fabricated as experimental electrode materials for rechargeable electro- chemical power cells and capacitors. Because they are free-standing, the wires in these mats are electrochemically accessible. The advantage of the mat- of-nanowires configuration, relative to other configurations of electrode materials, arises from the combination of narrowness and high areal number density of the wires. This combination offers both high surface areas for contact with electrolytes and short paths for diffusion of ions into and out of the electrodes, thereby making it possible to charge and discharge at rates higher than would otherwise be possible and, consequently, to achieve greater power densities.

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Fuels Containing Methane or Natural Gas in Solution

A blend of gasoline and natural gas offers advantages over alternative fuels. While exploring ways of producing better fuels for propulsion of a spacecraft on the Mars sample return mission, a researcher at Johnson Space Center (JSC) devised a way of blending fuel by combining methane or natural gas with a second fuel to produce a fuel that can be maintained in liquid form at ambient temperature and under moderate pressure. The use of such a blended fuel would be a departure for both spacecraft engines and terrestrial internal combustion engines. For spacecraft, it would enable reduction of weights on long flights. For the automotive industry on Earth, such a fuel could be easily distributed and could be a less expensive, more efficient, and cleaner-burning alternative to conventional fossil fuels.

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Improved BN Coatings on SiC Fibers in SiC Matrices

Outside debonding would be favored over inside debonding. Modifications of BN-based coatings that are used as interfacial layers between the fibers and matrices of SiC-fiber/SiC-matrix composite materials have been investigated to improve the thermomechanical properties of these materials. Such interfacial coating layers, which are also known as interphases (not to be confused with "interphase" in the biological sense), contribute to strength and fracture toughness of a fiber/matrix composite material by providing for limited amounts of fiber/matrix debonding and sliding to absorb some of the energy that would otherwise contribute to the propagation of cracks.

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Composite-Material Tanks With Chemically Resistant Liners

Liner materials are chosen for compatibility with reactive and/or unstable fluids. Lightweight composite-material tanks with chemically resistant liners have been developed for storage of chemically reactive and/or unstable fluids — especially hydrogen peroxide. These tanks are similar, in some respects, to the ones described in — Lightweight Composite-Material Tanks for Cryogenic Liquids — (MFS-31379), NASA Tech Briefs, Vol.25, No.1 (January, 2001), page 58; however, the present tanks are fabricated by a different procedure and they do not incorporate insulation that would be needed to prevent boil-off of cryogenic fluids.

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Brazing SiC/SiC Composites to Metals

Success depends on suitable process conditions and adequate titanium contents in brazing alloys. Experiments have shown that active brazing alloys (ABAs) can be used to join SiC/SiC composite materials to metals, with bond strengths sufficient for some structural applications. The SiC/SiC composite coupons used in the experiments were made from polymer-based SiC fiber preforms that were chemical-vapor- infiltrated with SiC to form SiC matrices. Some of the metal coupons used in the experiments were made from 304 stainless steel;others were made from oxygen-free, high-conductivity copper.

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Improved Charge-Transfer Fluorescent Dyes

Improved charge- transfer fluorescent dyes have been developed for use as molecular probes. These dyes are based on benzofuran nuclei with attached phenyl groups substituted with, variously, electron donors, electron acceptors, or combi- nations of donors and acceptors. Optionally, these dyes could be incorporated as parts of polymer backbones or as pendant groups or attached to certain surfaces via self-assembly-based methods.

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Wipes, Coatings, and Patches for Detecting Hydrazines

With suitable reformulation, other hazardous substances could also be detected. Three color-indicating devices have been conceived as simple, rapid, inexpensive means of detecting hazardous liquid and gaseous substances in settings in which safety is of paramount concern and it would be too time-consuming or otherwise impractical to perform detection by use of such instruments as mass spectrometers. More specifically, these devices are designed for detecting hypergolic fuels (in particular, hydrazines) and hypergolic oxidizers in spacecraft settings, where occasional leakage of these substances in liquid or vapor form occurs and it is imperative to take early corrective action to minimize adverse health effects. With suitable redesign, including reformulation of their color indicator chemicals, these devices could be adapted to detection of other hazardous substances in terrestrial settings (e.g., industrial and military ones).

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