Materials & Coatings

Formulating Precursors for Coating Metals and Ceramics

A protocol has been devised for formulating low-vapor-pressure precursors for protective and conversion coatings on metallic and ceramic substrates.

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Photocatalytic Coats in Glass Drinking-Water Bottles

According to a proposal, the insides of glass bottles used to store drinking water would be coated with films consisting of or containing TiO2. In the presence of ultraviolet light, these films would help to remove bacteria, viruses, and trace organic contaminants from the water.

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Isogrid Membranes for Precise, Singly Curved Reflectors

Reinforcing meshes of fibers would prevent wrinkles and ripples. A new type of composite material has been proposed for membranes that would constitute the reflective surfaces of planned lightweight, single curvature (e.g., parabolic cylindrical) reflectors for some radar and radio communication systems. The proposed composite materials would consist of polyimide membranes containing embedded grids of high strength (e.g., carbon) fibers. The purpose of the fiber reinforcements, as explained in more detail below, is to prevent wrinkling or rippling of the membrane.

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Nickel-Tin Electrode Materials for Nonaqueous Li-Ion Cells

Capacity densities exceed those of materials now commercially available for the same purpose. Experimental materials made from mixtures of nickel and tin powders have shown promise for use as the negative electrodes of rechargeable lithium-ion electrochemical power cells. During charging (or discharging) of a lithiumion cell, lithium ions are absorbed into (or desorbed from, respectively) the negative electrode, typically through an intercalation or alloying process. The negative electrodes (for this purpose, designated as anodes) in state-of-the-art Li-ion cells are made of graphite, in which intercalation occurs. Alternatively, the anodes can be made from metals, in which alloying can occur. For reasons having to do with the electrochemical potential of intercalated lithium, metallic anode materials (especially materials containing tin) are regarded as safer than graphite ones; in addition, such metallic anode materials have been investigated in the hope of obtaining reversible charge/discharge capacities greater than those of graphite anodes. However, until now, each of the tin-containing metallic anode formulations tested has been found to be inadequate in some respect.

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Patched Off-Axis Bending/Twisting Actuators for Thin Mirrors

Two documents present updates on thin-shell, adjustable, curved mirrors now being developed for use in spaceborne imaging systems.  These mirrors at an earlier stage of development were reported in “Nanolaminate Mirrors With Integral Figure-Control Actuators” (NPO-30221), NASA Tech Briefs, Vol. 26, No. 5 (May 2002), page 80. To recapitulate: These mirrors comprise metallic film reflectors on nanolaminate substrates that contain “in-plane” actuators for controlling surface figures with micronlevel precision. The actuators are integral parts of the mirror structures, typically fabricated as patches that are bonded onto the rear (nonreflective) surfaces of the mirror shells. The current documents discuss mathematical modeling of mirror deflections caused by actuators arranged in unit cells distributed across the rear mirror surfaces. One of the documents emphasizes an actuator configuration in which a mirror surface is divided into hexagonal unit cells. Each unit cell contains four rectangular actuator patches in an off-axis cruciform pattern to induce a combination of bending and twisting. For deflections to reduce certain optical aberrations, it is found that, relative to other configurations, this configuration involves a smaller areal density of actuators.

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Molybdate Coatings for Protecting Aluminum Against Corrosion

These coatings show promise, but further development is needed. Conversion coatings that comprise mixtures of molybdates and several additives have been subjected to a variety of tests to evaluate their effectiveness in protecting aluminum and alloys of aluminum against corrosion. Molybdate conversion coatings are under consideration as replacements for chromate conversion coatings, which have been used for more than 70 years. The chromate coatings are highly effective in protecting aluminum and its alloys against corrosion but are also toxic and carcinogenic. Hexavalent molybdenum and, hence, molybdates containing hexavalent molybdenum, have received attention recently as replacements for chromates because molybdates mimic chromates in a variety of applications but exhibit significantly lower toxicity.

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Synthesizing Diamond From Liquid Feedstock

Precise proportioning of feedstock gases is not necessary. A relatively economical method of chemical vapor deposition (CVD) has been developed for synthesizing diamond crystals and films. Unlike prior CVD methods for synthesizing diamond, this method does not require precisely proportioned flows of compressed gas feedstocks or the use of electrical discharges to decompose the feedstocks to obtain free radicals needed for deposition chemical reactions. Instead, the feedstocks used in this method are mixtures of common organic liquids that can be prepared in advance, and decomposition of feedstock vapors is effected simply by heating.

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