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Environmentally Safer, Less Toxic Fire-Extinguishing Agents

Water droplets would be microencapsulated in flame-retardant polymers. Fire-extinguishing agents comprising microscopic drops of water micro- encapsulated in flame-retardant polymers have been proposed as effective, less toxic, non-ozone- depleting, non-global- warming alternatives to prior fire-extinguishing agents. Among the prior fire-extinguishing agents are halons (various halocarbon fluids), which are toxic and contribute both to depletion of upper- atmospheric ozone and to global warming. Other prior fire-extinguishing agents are less toxic and less environmentally harmful but, in comparison with halons, are significantly less effective in extinguishing fires.

Posted in: Materials, Briefs

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Multiaxial Temperature- and Time-Dependent Failure Model

This model should be applicable to a variety of materials. A temperature- and time-dependent mathematical model predicts the conditions for failure of a material subjected to multiaxial stress. The model was initially applied to a filled epoxy below its glass-transition temperature, and is expected to be applicable to other materials, at least below their glass-transition temperatures. The model is justified simply by the fact that it closely approximates the experimentally observed failure behavior of this material: The multiaxiality of the model has been confirmed (see figure) and the model has been shown to be applicable at temperatures from —20 to 115 °F (–29 to 46 °C) and to predict tensile failures of constant-load and constant-load-rate specimens with failure times ranging from minutes to months.

Posted in: Materials, Briefs

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Oxide Protective Coats for Ir/Re Rocket Combustion Chambers

An improved material system has been developed for rocket engine combustion chambers for burning oxygen/hydrogen mixtures or novel monopropellants, which are highly oxidizing at operating temperatures. The baseline for developing the improved material system is a prior iridium/rhenium system for chambers burning nitrogen tetroxide/monomethyl hydrazine mixtures, which are less oxidizing. The baseline combustion chamber comprises an outer layer of rhenium that provides structural support, plus an inner layer of iridium that acts as a barrier to oxidation of the rhenium. In the improved material system, the layer of iridium is thin and is coated with a thermal fatigue-resistant refractory oxide (specifically, hafnium oxide) that serves partly as a thermal barrier to decrease the temperature and thus the rate of oxidation of the rhenium. The oxide layer also acts as a barrier against the transport of oxidizing species to the surface of the iridium. Tests in which various oxygen/hydrogen mixtures were burned in iridium/rhenium combustion chambers lined with hafnium oxide showed that the operational lifetimes of combustion chambers of the improved material system are an order of magnitude greater than those of the baseline combustion chambers.

Posted in: Materials, Briefs, TSP

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Simplified Waterproofing of Aerogels

Silanization is performed in a single treatment at moderate temperature and pressure. A relatively simple silanization process has been developed for waterproofing or rewaterproofing aerogels, xerogels, and aerogel/tile composites, and other, similar low-density, highly microporous materials. Such materials are potentially attractive for a variety of applications — especially for thermal-insulation panels that are required to be thin and lightweight. Unfortunately, such materials are also hydrophilic and tend to collapse after adsorbing water from the air. Hence, an effective means of waterproofing is necessary to enable practical exploitation of aerogels and the like.

Posted in: Materials, Briefs, TSP

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Improved Thermal-Insulation Systems for Low Temperatures

Efficient, robust insulation for soft vacuum. Improved thermal- insulation materials and structures and the techniques for manufacturing them are undergoing development for use in low-temperature applications. Examples of low- temperature equipment for which these thermal insulation systems could provide improved energy efficiency include storage tanks for cryogens, superconducting electric- power- transmission equipment, containers for transport of food and other perishable commodities, and cold boxes for low-temperature industrial processes. These systems could also be used to insulate piping used to transfer cryogens and other fluids, such as liquefied natural gas, refrigerants, chilled water, crude oil, or low-pressure steam.

Posted in: Materials, Briefs, TSP

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Stable, Thermally Conductive Fillers for Bolted Joints

A commercial structural epoxy [Super Koropon (or equivalent)] has been found to be a suitable filler material for bolted joints that are required to have large thermal conductances. The contact area of such a joint can be less than 1 percent of the apparent joint area, the exact value depending on the roughnesses of the mating surfaces. By occupying the valleys between contact peaks, the filler widens the effective cross section for thermal conduction. In comparison with prior thermal joint-filler materials, the present epoxy offers advantages of stability, ease of application, and —as a byproduct of its stability — lasting protection against corrosion. Moreover, unlike silicone greases that have been used previously, this epoxy does not migrate to contaminate adjacent surfaces. Because this epoxy in its uncured state wets metal joint surfaces and has low viscosity, it readily flows to fill the gaps between the mating surfaces: these characteristics affect the overall thermal conductance of the joint more than does the bulk thermal conductivity of the epoxy, which is not exceptional. The thermal conductances of metal-to-metal joints containing this epoxy were found to range between 5 and 8 times those of unfilled joints.

Posted in: Materials, Briefs, TSP

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Antistatic Polycarbonate/Copper Oxide Composite

Surface resistance lies in the desired range. A composite material consisting of polycarbonate filled with copper oxide has been found to be suitable as an antistatic material. This material was developed to satisfy a requirement for an antistatic material that has a mass density less than that of aluminum and that exhibits an acceptably low level of outgassing in a vacuum.

Posted in: Materials, Briefs, TSP

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