An acid mixture bubbles atop a silicon wafer as it etches holes and works toward turning the wafer black. (Dennis Schroeder/NREL)
DOE's National Renewable Energy Laboratory (NREL) has granted Natcore Technology Inc. a patent license agreement to develop new black silicon products. Natcore and NREL also will enter a Cooperative Research and Development Agreement (CRADA) to develop commercial prototypes based on NREL’s black silicon inventions.

The "Black Silicon Nanocatalytic Wet-Chemical Etch" emerged from work by NREL photovoltaic researchers that demonstrated that black silicon solar cells, which have been chemically etched to appear black, better absorb the sun’s energy. The inexpensive, one-step method reduces light reflection from silicon wafers to less than 2 percent, and promises to reduce manufacturing production cost and capital expense.

Any photons reflected from the surface of a solar cell are wasted. To reduce reflected sunlight and increase cell efficiency, NREL scientists invented the antireflection process that turns silicon wafers black so they absorb 98 percent of solar radiation. Today’s solar cells absorb about 95 percent of the sun’s radiation.

The much-lower-cost recipe is still a few tenths of a percent less efficient than the best of the conventional cells. However, the black silicon prevents reflection of low-angle morning and afternoon sunlight far better, which means a jump in photovoltaic efficiency of at least 1 percentage point can be achieved. NREL estimates that its method can reduce processing costs by 4 to 8 percent, resulting in overall savings in solar cell manufacturing of 1 to 3 percent, making black silicon particularly appealing.

(NREL)