An apparatus has been developed as a means of controlling the partial pressure of CO2 (pCO2) in air in a closed or semiclosed environmental system. The apparatus takes CO2 from the air in a source chamber and supplies the CO2, at a regulated partial pressure, to the air in a sink chamber. In the original intended application, the chambers would be located aboard a spacecraft: the source chamber would be inhabited by crewmembers, and the sink chamber would be a plant-growth chamber. Apparatuses like this one could also be used to control pCO2 in research plant-growth chambers on Earth.

The Alkanolamine Solution in the Reservoir acts as a buffer for CO2: Its Its temperature is varied to make it store or release CO2 as needed to maintain a required pCO2.
In comparison with prior pCO2-regulating apparatuses built around sources of compressed gases, mass-flow controllers, CO2 sensors, and/or single-use sorbents, this apparatus consumes less expendable material and is relatively simple and inexpensive. In this apparatus (see figure), CO2 is gathered from the source atmosphere, across a semipermeable membrane, into a reservoir that contains an aqueous solution of an alkanolamine. Depending on conditions, such a solution absorbs or desorbs CO2; the CO2 load in the solution depends on the pCO2, duration of exposure, and temperature. From the solution, CO2 is transferred, as needed, across another semipermeable membrane, to the atmosphere in the sink chamber. Because the release of CO2 to the atmosphere in the sink chamber is an equilibrium process, the resulting pCO2 in the sink chamber depends on both the CO2 loading of the alkanolamine and the temperature and can be controlled, within specified limits, by changing the temperature of the alkanolamine solution.

In the case of an inhabited source chamber, the pCO2 in that chamber can generally be expected to exceed the pCO2 required for a sink chamber in which plants are to be grown. In such a case, CO2 can be gathered periodically from the source chamber to maintain the required CO2 loading of the solution while the required pCO2 in the plant-growth chamber is maintained through equilibrium exchange. Because of the large CO2 capacity of the alkanolamine, stable control of the pCO2 in the plant-growth chamber is easily achieved.

When the pCO2 in the source chamber is less than the pCO2 required in the sink chamber, temperature-dependent solubility is used to pump CO2 against its concentration gradient: Inasmuch as the equilibrium pCO2 above the alkanolamine solution increases with temperature, CO2 is gathered through the membrane on the source-chamber side at a temperature lower than that at which it is released through the other membrane on the plant-growth-chamber side.

The absorption of CO2 in an alkanolamine solution takes place through reversible ionization reactions that change the relative abundance of electrically conductive species in the solution. As a result, there is a relationship between the electrical conductance of the solution and its CO2 load. This relationship is exploited in the present apparatus: The electrical conductance measured at a given temperature is taken as an indication of the CO2 loading of the solution and, by extension, of the equilibrium pCO2 of the atmosphere in contact with the solution.

This work was done by Jeffrey L. DeHart, James R. Akse, and James E. Atwater of Umpqua Research Co. for Johnson Space Center. For more information, contact the Johnson Commercial Technology Office at (281) 483-3809.