NASA Technologist Mahmooda Sultana has been leading the development of tiny graphene sensors. Because of the material’s extreme sensitivity, graphene-based sensors have a wide range of possible space applications, including the detection of strain in composite materials and the discovery of trace gases in planetary bodies.

Goddard technologist Mahmooda Sultana investigates new applications for graphene, a technology with unique physical characteristics that are ideal for spaceflight use. (Image Credit: NASA/Pat Izzo)
Sensor Technology spoke to Dr. Sultana this month to learn more about the nanotechnologies currently being built at Goddard Space Flight Center.

Sensor Technology: What makes graphene an ideal material for sensors?

Mahmooda Sultana: It’s the combination of graphene’s properties that makes it ideal for sensors. First of all, these two-dimensional materials have the highest surface-to-volume ratio. All the atoms are exposed to the surface. Along with that, graphene also has very low thermal noise and superior electrical properties, which allows us to measure the smallest of changes in electrical properties. For example, singlemolecule detection has been demonstrated with graphene. In addition, graphene is radiation hard due to the minute cross-sectional area, which makes it ideal for space applications.

Sensor Technology: What do these sensors look like?

Sultana: These are very small sensors. Our first prototype is about a 1-cm by 1-cm chip, with ten sensing elements. You can actually fit a lot more sensor elements than that; we haven’t optimized the real estate yet. These are tens-of-microns-sized sensors that have leads or contact lines. We basically wirebond those contacts to a printed circuit board. Then, you can use a pin connector to read off the data.

Sensor Technology: What is being measured?

Sultana: For these chemical sensors, we’re doing four probe measurements. We apply a small current and measure the voltage drop across the graphene element. The voltage drop is proportional to the resistance of graphene. When our target gas molecules adsorb onto graphene, the resistance changes. It’s a very simple electrical measurement, which makes these devices robust.

Sensor Technology: How can the sensors detect strain?

Sultana: We’re developing graphenebased sensors for strain sensing as well. These could be used for structural health monitoring of composite materials on spacecraft and cryotanks. If there is an impact during launch or while in space that affects our instruments, we want to know, so we can tell if we should still trust the data.

Sensor Technology: How are they placed on the structure?

A diagram of a graphene sensor.
Sultana: One of the advantages of these 2D sensors is that we can embed them in the composite structure. They are very thin, only about a few angstroms, so they can be easily integrated with composite materials. Due to the small size, we can actually put in a network of sensors, so we can tell which part of the structure suffered damage.

Sensor Technology: What kinds of chemical sensing applications are possible?

Sultana: I’m very interested in space applications related to planetary science, heliophysics, and earth science. For example, in planetary science, you can imagine spreading many of these tiny sensors over a planetary body and getting spatial/temporal data on various gases of importance. There are many ground-based applications as well, including in situ process monitoring, environmental pollutant monitoring, detection of hazardous gas in chemical plants or explosives in airports and public buildings, and medical diagnosis.

Sensor Technology: What about Mars exploration?

Sultana: The analytical tools sent on rovers can only measure one data point at a time. Typically, scientists pick a location to measure, and then the rover has to travel to that location to take measurements. The number of data points that you can measure this way is very limited, and you can’t track the concentration of gas species over an extended period of time.

However, with these tiny detectors, we can afford to send many of them at once, and spread a network across a planet like Mars. We’ll be able to simultaneously measure trace gases at various spatial locations over an extended period of time. Recent evidence indicates spatial and temporal variability of important gases, such as methane, on Mars. We can characterize such seasonal variations with a network of graphene sensors.

Sensor Technology: Can the sensors detect methane?

Sultana: Methane is one of our target gases, and we are currently working towards making our sensors selective to methane. It is a species of great interest on Mars, as well as other oxidized planetary environments, because it can be an indicator of photochemistry, hydrothermal activity, or microbial metabolism.