The performance of flexible large-area organic photodiodes has advanced to the point that they can now offer advantages over conventional silicon photodiode technology, particularly for applications such as biomedical imaging and biometric monitoring that require detecting low levels of light across large areas. The low-noise, solution-processed, flexible organic devices offer the ability to use arbitrarily shaped, large-area photodiodes to replace complex arrays that would be required with conventional silicon photodiodes, which can be expensive to scale up for large-area applications. The organic devices provide performance comparable to that of rigid silicon photodiodes in the visible light spectrum — except in response time.
“What we have achieved is the first demonstration that these devices, produced from solution at low temperatures, can detect as little as a few hundred thousand photons of visible light every second, similar to the magnitude of light reaching our eye from a single star in a dark sky,” said Canek Fuentes-Hernandez, principal research scientist in the School of Electrical and Computer Engineering at the Georgia Institute of Technology. “The ability to coat these materials onto large-area substrates with arbitrary shapes means that flexible organic photodiodes now offer some clear advantages over state-of-the-art silicon photodiodes in applications requiring response times in the range of tens of microseconds.”
Organic electronic devices are based on materials fabricated from carbon-based molecules or polymers instead of conventional inorganic semiconductors such as silicon. The devices can be made using simple solution and inkjet printing techniques instead of the expensive and complex processes involved in the manufacturing of conventional electronics. The technology is now widely used in displays, solar cells, and other devices.
The organic photodiodes use polyethylenimine, an amine-containing polymer surface modifier found to produce air-stable, low work-function electrodes in photovoltaic devices developed in the laboratory of Bernard Kippelen, Joseph M. Pettit Professor at Georgia Tech. The use of polyethylenimine was also shown to produce photovoltaic devices with low levels of dark current — the electrical current that flows through a device even in the dark. This meant the materials could be useful in photodetectors for capturing faint signals of visible light.
One application for the new devices is in pulse oximeters now placed on fingers to measure heart rate and blood oxygen levels. Organic photodiodes may allow multiple devices to be placed on the body and operate with 10 times less light than conventional devices. This could enable wearable health monitors to produce improved physiological information and continuous monitoring without frequent battery changes. Other potential applications include human-computer interfaces such as touchless gesture recognition and controls.
A future application is detection of ionizing radiation by scintillation — a flash of light emitted by a phosphor when struck by a high energy particle. Lowering the level of light that can be detected would improve the sensitivity of the device, allowing it to detect lower levels of radiation. Detecting radiation emitted from vehicles or cargo containers requires a large detector area, which would be easier to make from organic photodiodes than from arrays of silicon photodiodes.
Organic photodiodes could have similar advantages in X-ray equipment, where doctors want to use the smallest level of radiation possible to minimize the dose delivered to the patient. Here again, sensitivity, large area, and flexible form factor should give organic photodiodes an advantage over silicon-based arrays.
The organic photodiodes can show electronic noise current values in the tens of femtoampere range and noise equivalent power values of a couple of hundreds of femtowatt. Key performance factors of the organic photodiodes compare well with silicon except in the area of response time, where researchers are working on a hundred-fold improvement to enable future applications.
“Organic thin films absorb light more efficiently than silicon, so the overall thickness you need to absorb that light is very small,” Kippelen said. “Even if you scale their area up, the overall volume of your detector remains small with organics. If you increase the area of a silicon detector, you have a larger volume of materials that at room temperature will generate a lot of electronic noise.”
The photodiodes made in Kippelen’s lab use an active layer just 500 nanometers thick. A gram of the material, roughly the size of a fingertip, could coat the surface of an office desk.