Innovators at NASA's Glenn Research Center have developed a new Nickel Titanium (NiTi) shape memory alloy (SMA) with additions of Hafnium (Hf) and Zirconium (Zr) that offers a broader transformation temperature range and greater dimensional stability than any other SMA on the market. In spite of their many unique properties, broad commercial success of SMAs has remained elusive due to limited phase transformation temperatures and dimensional instability in high cycle applications.

Glenn's innovation solves these limitations by a) tailoring transformation temperatures through molecular composition, heat treatments, or micro-structural refinements; and b) engineering inherent dimensional stability through composition control and processing methods. The result is an exceptionally strong SMA that is heat-treatable and can be tuned for high, ambient, or sub-zero transformation temperatures as needed, making it a game-changer in the SMA industry with practical applications to a variety of industries including aerospace, automotive, biomedical, and more.

SMAs are important multifunctional materials for the development of adaptive engineering structures. They exhibit a high work output that is competitive with, or superior to, conventional hydraulic, pneumatic, or electromagnetic actuators. While highly promising, SMAs are not always a practical alternative to conventional actuators because of their limited phase transformation temperatures and dimensional instability.

Unlike traditional binary NiTi SMAs, Glenn's Ni-Ti-Hf-Zr SMA includes secondary nanoscale precipitate phases that offer inherent dimensional stability to the material. Consequently, there is minimal to no need for training, resulting in much faster production times, lower processing costs, and a finished product with superior work outputs and better operational life. These Ni-rich alloys can be produced by vacuum induction melting, vacuum arc melting, vacuum arc remelting, and induction skull melting.

Perhaps the most exciting characteristic of Glenn's SMA, however, is its ability to achieve a broad range of transformation temperatures suitable for high-temperature (100 to 300 °C), ambient, and sub-ambient temperature applications nearing -100 °C. Furthermore, these temperatures can be tailored and fine-tuned though heat treatment to fit the needed parameters for the application of interest. In contrast, traditional NiTi SMAs exhibit fixed phase transformation at temperatures from slightly below room temperature to around 100 °C. Glenn's Ni-Ti-Hf-Zr SMA opens the door to countless applications that can benefit from the unique properties of SMAs but require high durability and extreme temperature capability.

Contact the Glenn Technology Transfer Office at This email address is being protected from spambots. You need JavaScript enabled to view it. or 216-433-3484. Follow this link here  for more information.

Tech Briefs Magazine

This article first appeared in the December, 2019 issue of Tech Briefs Magazine.

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