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UV Resonant Raman Spectrometer With Multi-Line Laser Excitation

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A Raman spectrometer employs two or more UV (ultraviolet) laser wavelengths to generate UV resonant Raman (UVRR) spectra in organic samples. Resonant Raman scattering results when the laser excitation is near an electronic transition of a molecule, and the enhancement of Raman signals can be several orders of magnitude. In addition, the Raman cross-section is inversely proportional to the fourth power of the wavelength, so the UV Raman emission is increased by another factor of 16, or greater, over visible Raman emissions. The Raman-scattered light is collected using a high-resolution broadband spectrograph. Further suppression of the Rayleigh-scattered laser light is provided by custom UV notch filters.

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