
A team of scientists has created a new shape-changing polymer that could transform how future soft materials are constructed.
Made using a material called a liquid crystalline elastomer (LCE), a soft rubber-like material that can be stimulated by external forces like light or heat, the polymer is so versatile that it can move in several directions.
Its behavior, which resembles the movements of animals in nature, includes being able to twist, tilt left and right, shrink and expand, said Xiaoguang Wang, co-author of the study and an assistant professor in chemical and biomolecular engineering at The Ohio State University.
“Liquid crystals are materials that have very unique characteristics and properties that other materials cannot normally achieve,” said Wang. “They’re fascinating to work with.”
This new polymer’s ability to change shapes could make it useful for creating soft robots or artificial muscles, among other high-tech devices in medicine and other fields.
Today, liquid crystals are most often used in TVs and cell phone displays, but these materials often degrade over time. But with the expansion of LEDs, many researchers are focused on developing new applications for liquid crystals.
Unlike conventional materials that can only bend in one direction or require multiple components to create intricate shapes, this team’s polymer is a single component that can twist in two directions. This property is tied to how the material is exposed to temperature changes to control the molecular phases of the polymer, said Wang.

“Liquid crystals have orientational order, meaning they can self-align,” he said. “When we heat the LCE, they transition into different phases causing a shift in their structure and properties.”
This means that molecules, tiny building blocks of matter, that were once fixed in place can be directed to rearrange in ways that allow for greater flexibility. This aspect may also make the material easier to manufacture, said Wang.
The study was recently published in the journal Science.
If scaled up, the polymer in this study could potentially advance several scientific fields and technologies, including controlled drug delivery systems, biosensor devices, and as an aid in complex locomotion maneuvers for next-generation soft robots.
One of the study’s most important findings reveals the three phases that the material goes through as its temperature changes, said Alan Weible, co-author of the study and a graduate fellow in chemical and biomolecular engineering at Ohio State. Throughout these phases, molecules shift and self-assemble into different configurations.
“These phases are one of the key factors we optimized to allow the material ambidirectional shape deformability,” he said. In terms of size, the study further suggests that the material can be scaled up or down to adapt to nearly any need.
“Our paper opens a new direction for people to start synthesizing other multiphase materials,” said Wang.
Researchers note that with future computational advances, their polymer could eventually be a useful tool for dealing with delicate situations, like those that require the precise design of artificial muscles and joints or upgrading soft nanorobots needed for complex surgeries.
“In the next few years, we plan to develop new applications and hopefully break into the biomedical field,” said Weible. “There’s a lot more we can explore based on these results.”
Here is an exclusive Tech Briefs interview, edited for length and clarity, with Weible.
Tech Briefs: What was the biggest technical challenge you faced while developing this shape-changing polymer?
Weible: This experiment has been going on for over six years, so there are many. But I believe it's finding the correct linkage in the liquid crystal polymer networks, as well as actually understanding what was being made. It took a little bit to understand that it's not going from the smectic A phase, but it's transitioning into a phase that's called a chevron smectic C — rather than parallell layers, it goes into the chevron shape. But it's also just developing the polymer networks and getting an understanding of what they're actually doing.
Tech Briefs: You said it's been ongoing for over six years, but what was the catalyst for this project? How did it all get started?
Weible: My professor worked with Dr. Abbott when he was at the University of Wisconsin Madison and then when he went and did his postdoc, they were doing some different things. But, honestly, he's the one that came up with the idea because he just saw it. I believe it's mostly because he wanted to understand when you can give liquid crystals more rotational freedom and and when you can create an aligned network of polymers — what you can do with them.
Tech Briefs: Can you explain simple terms how it works?
Weible: They make polymers basically in a little column from a mold. Little liquid crystal molecules can be affected by temperature or light or even a magnetic field sometimes. When they're at the lowest temperature, which is the smectic chevron, they align into a chevron shape, which is pointed like an arrow top. When you increase the temperature, it will transition from this pointed area to an area of flat layers, which will be the smectic A. Then, as you continue to heat it, it no longer has orientational order and positional order — it goes into a fluid. It's supposed to be isotropic, which is no order, no positional order, and no orientational order. So, if it was outside of a polymer, it would behave like a fluid, like water or oil. But in this case, with the polymer network, it goes from a nice structured layer like a lamella, into a random coil.
Tech Briefs: Do you have plans for any further research, work, etc.?
Weible: The main idea would be trying to expand into soft robotics situations. Because most of the soft robotics right now can only do one direction. So, if you heat it, you may be able to clamp it. But, with ours, we may be able to open it up and have new directions of how you can apply it. So, hopefully it can possibly be used in something like joints in the robotics. There are a lot of things we can try. It takes a long time to develop these ideas, so hopefully we can get one rolling and get that out.